南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

华南陆缘高热流区的壳幔温度结构与动力学背景          下载免费PDF全文

张健  王蓓羽  唐显春  董淼  艾依飞 《地球物理学报》2018,61(10):3917-3932

华南陆缘是我国重要的矿产、地热资源区.晚中生代以来，在太平洋板块西向俯冲，地幔热对流活动共同作用下，该区出现多期岩浆-热事件和大规模爆发式成矿作用.在前人研究基础上，本文利用地表热流观测资料、地震剪切波资料、重力位球谐系数，计算了壳-幔温度结构，分析了动力学背景.计算结果表明：华南陆缘东南沿海地带，地壳10 km以浅温度达200℃以上，居里点温度475℃，莫霍面平均温度550℃.地壳浅层较热，花岗岩中放射性元素衰变放热是地壳浅层地下水热活动的重要热源，但地壳总体温度不高，为"冷壳热幔"型热结构.地幔中，90 km深度，温度950~1250℃；120 km深度，温度1050~1400℃；150 km深度，温度1200~1450℃；220 km深度，温度1500~1700℃."热"岩石圈底界深度在110~150 km之间，西深东浅.岩石圈内，地幔应力场为挤压-伸展相间格局；岩石圈之下，地幔应力场为一个以南昌为中心、长轴NE-SW向的椭圆.分析认为，晚中生代以来，太平洋板块的西向俯冲，导致华南陆缘在区域性SE向地幔对流背景上叠加局域性不稳定热扰动，在175~85Ma期间，上地幔物质向上流动，形成不同的岩浆活动高峰期.同时，岩石圈地幔受俯冲洋壳流体的影响，含水量高，黏度小，在地幔流切向应力场作用下，岩石圈底界由西向东"波浪"状减薄.现今岩石圈之下仍具备地幔小尺度热对流温度条件，但除地表浅层外，地壳整体温度不高，岩石圈构造稳定.  相似文献   

3D P-WAVE VELOCITY STRUCTURE AT THE NORTHEASTERN MARGIN OF ORDOS BLOCK     

HAN Xiao-ming  Liu Fang  ZHANG Fan  CHEN Li-feng  LI Juan  LI Shuan-hu  YANG Hong-ying 《地震地质》2018,40(1):215-231

Using the 7 100 absolute first arrivals of P waves and 91 513 relative P arrival times of 726 events at the northeastern margin of the Ordos block since 2009, the 3D fine structure of P wave velocity within the depth of 15km in the crust was inverted by the double difference seismic tomography method. The results show that there exist obvious high-speed continuous bodies in the northwest of the study area, and their lateral areas increase gradually with depth, while the velocity of east and south is relatively low. The velocity inhomogeneity exists and differs at different depths. The lateral differences of velocity are related to seismicity and faults. The 5~15km depth profile shows that earthquakes tend to occur in the area with relatively high velocity or high speed transition zones, which to some extent reflects the fragility of regional crustal media and the strong differential movement of faults in vertical and horizontal directions where the crust body is easy to absorb and store strain energy and generate major earthquakes. A "Y"-shape low-velocity channel is present in the lower crust around Liangcheng, corresponding to the NW-trending Heilaoyao-Shahukou fault set, which may reveal the migration path of the Late Tertiary-Quaternary basalt eruption. The Helingeer M6.2 earthquake in 1976 was related to the formation of the locking section of the thermal welding in this area. The three-dimensional fine structure of P wave velocity presented in this paper provides intuitive seismological evidence for physical and chemical properties of crustal media and the deep tectonic environment of earthquake preparation.  相似文献   

Intermediate to Long-term Estimation of Strong Earthquake Risk Areas in the Chinese Mainland Based on Geodesic Measurements     

Zhang Jing  Zhu Yiqing  Wu Yanqiang  Zhang Xi  Yang Guohua 《中国地震研究》2018,32(2):153-172

Based on previous research results, present-day crustal deformation and gravity fields in the Chinese mainland are analyzed using the GPS data, leveling, gravity and cross-fault deformations. We analyzed strain accumulation of the major faults, and identified locked or high strain accumulation segments. Combining the effects of large earthquakes in the study area, the long-term (decade) probability of large earthquakes in the Chinese mainland is estimated.  相似文献   

山东昌邑国家级海洋生态特别保护区生态环境现状及管护对策研究          下载免费PDF全文

隽云昌  刘国宁  张颖  张守本  李秋霞  宋秀凯  马元庆  秦华伟  张志  吴倩倩  付新华 《海洋开发与管理》2018,35(7):63-71

山东昌邑国家级海洋生态特别保护区是目前国内唯一以柽柳林生态系统为主要管理和保护对象的国家级海洋保护区。为系统、全面地了解保护区内生态环境和保护物种的变化趋势,文章对山东昌邑国家级海洋生态特别保护区生态环境现状进行了监测与评价,并根据评价结果,分析了保护区保护与管理中存在的问题。研究表明,该保护区生态环境一直处于亚健康状态,为促进保护及管护,提出了加强保护区生态建设,改变保护区开发利用模式;加强能力建设,实现保护区动态监控;协调发展与保护的关系,实现资源可持续利用;大力开展柽柳生态修复,恢复柽柳的资源状况的对策建议。  相似文献   

南海北部东沙海域天然气水合物分解事件及其与海底滑塌的关系     

黄怡  王淑红  颜文  程俊 《热带海洋学报》2018,37(4):61-69

东沙海域是南海北部一个重要的天然气水合物成藏区, 其陆坡广泛发育滑塌构造。文章对采自东沙陆坡中部973-4柱样和下部平坦区973-5柱样开展了沉积学粒度、底栖有孔虫种属特征和稳定同位素等的综合分析。研究结果表明: 两个柱样中底栖有孔虫的δ¹³C在末次冰期均出现明显负偏现象, 同时δ¹⁸O增高, 指示该时期东沙海域存在持续的天然气水合物分解事件; 末次冰消期以来, δ¹³C负偏现象逐渐消失, δ¹⁸O值降低, 可能是由于海平面上升阻止了天然气水合物分解。973-4柱样仅在末次盛冰期对应层位440~600cm段存在明显的滑塌沉积, 且该层段对应的特征底栖有孔虫Uvigerina spp.和Bulimina spp.的数量突增, 推测该区的海底滑塌可能是由于末次盛冰期海平面大幅度下降引起天然气水合物大量分解诱发所致; 973-5柱样同样记录到了海底滑塌现象, 但其滑塌沉积晚于973-4柱样的滑塌时间, 且其规模较小。  相似文献   

Wintertime rates of net primary production and nitrate and ammonium uptake in the southern Benguela upwelling system     

RF Flynn  JM Burger  K Pillay 《African Journal of Marine Science》2018,40(3):253-266

The elevated levels of primary productivity associated with eastern boundary currents are driven by nutrient- rich waters upwelled from depth, such that these regions are typically characterised by high rates of nitrate-fuelled phytoplankton growth. Production studies from the southern Benguela upwelling system (SBUS) tend to be biased towards the summer upwelling season, yet winter data are required to compute annual budgets and understand seasonal variability. Net primary production (NPP) and nitrate and ammonium uptake were measured concurrently at six stations in the SBUS in early winter. While euphotic zone NPP was highest at the stations nearest to the coast and declined with distance from the shore, a greater proportion was potentially exportable from open-ocean surface waters, as indicated by the higher specific nitrate uptake rates and f-ratios (ratio of nitrate uptake to total nitrogen consumption) at the stations located off the continental shelf. Near the coast, phytoplankton growth was predominantly supported by ammonium despite the high ambient nitrate concentrations. Along with ammonium concentrations as high as 3.6 µmol l^–1, this strongly suggests that nitrate uptake in the inshore SBUS, and by extension carbon drawdown, is inhibited by ammonium, at least in winter, although this has also been hypothesised for the summer.  相似文献   

Tectonometamorphic evolution of the Atbashi high‐P units (Kyrgyz CAOB,Tien Shan): Implications for the closure of the Turkestan Ocean and continental subduction–exhumation of the South Kazakh continental margin          下载免费PDF全文

Chloé Loury  Yann Rolland  Stéphane Guillot  Pierre Lanari  Clément Ganino  Raphael Melis  Anthony Jourdon  Carole Petit  Olivier Beyssac  Sylvain Gallet  Patrick Monié 《Journal of Metamorphic Geology》2018,36(8):959-985

The South Tien Shan (STS) belt results from the last collision event in the western Central Asian Orogenic Belt (CAOB). Understanding its formation is of prime importance in the general framework of the CAOB. The Atbashi Range preserves high‐P (HP) rocks along the STS suture, but still, its global metamorphic evolution remains poorly constrained. Several HP units have been identified: (a) a HP tectonic mélange including boudins of mafic eclogites in a sedimentary matrix, (b) a large (>100 km long) high‐P metasedimentary unit (HPMU) and (c) a lower blueschist facies accretionary prism. Raman Spectroscopy on carbonaceous material combined with phengite and chlorite multiequilibria and isochemical phase diagram modelling indicates that the HPMU recorded homogeneous P–T conditions of 23–25 kbar and 560–570°C along the whole unit. ⁴⁰Ar/³⁹Ar dating on phengite from the HPMU ranges between 328 and 319 Ma at regional scale. These ages are interpreted as (re‐) crystallization ages of phengite during T_max conditions at a pressure range of 20–25 kbar. Thermobarometry on samples from the HP tectonic mélange provides similar metamorphic peak conditions. Thermobarometry on the blueschist to lower greenschist facies accretionary prism indicates that it underwent P–T conditions of 5–6 kbar and 290–340°C, highlighting a 17–20 kbar pressure gap between the HPMU‐tectonic mélange units and the accretionary prism. Comparison with available geochronological data suggests a very short time span between the prograde path (340 Ma), HP metamorphic peak (330 Ma), the T_max (328–319 Ma) and the final exhumation of the HPMU (303–295 Ma). Extrusion of the HPMU, accommodated by a basal thrust and an upper detachment, was driven by buoyant forces from 70–75 km up to 60 km depth, which directly followed continental subduction and detachment of the HPMU. At crustal depths, extrusion was controlled by collisional tectonics up to shallow levels. Lithological homogeneity of the HPMU and its continental‐derived character from the North Tien Shan suggest this unit corresponds to the hyper‐extended continental margin of the Kazakh continent, subducted southward below the north continental active margin of the Tarim craton. Integration of the available geological data allows us to propose a general geodynamic scenario for Tien Shan during the Carboniferous with a combination of (a) N‐dipping subduction below the Kazakh margin of Middle Tien Shan until 390–340 Ma and (b) S‐dipping subduction of remaining Turkestan marginal basins between 340 and 320 Ma.  相似文献   

海南省连片贫困地区农户致贫风险分析   总被引：4，自引：1，他引：3  

张金萍  宋伟  林丹  余珍鑫  李庭筠  罗邱戈  程叶青 《地理科学》2020,40(4):608-616

农村贫困与减贫是世界性难题,也是中国各级政府高度重视并着力解决的重大民生问题。基于农户及致贫风险的文献梳理,从区位、社会和劳动力3个要素维度构建了农户致贫风险分析的二元Logistic回归模型。采用484户农户问卷调查数据,分析了海南省连片贫困地区农户的致贫风险,提出有效减贫和持续发展对策。研究发现:① 海南连片贫困地区生态环境良好但贫困发生率较高,家庭劳动力较充裕但受教育水平较低,子女教育支出负担重,因病因残致贫比例较高,女性务工人口较多,农户自身脱贫致富的发展动力不足。② 海拔高度200 m以下、男性户主、拥有残疾或患病成员、务工人口比例低、女性务工人员占比高、以及单位劳动力供养学生数高的农户具有更大的致贫风险。③ 研究未发现女性户主、少数民族、低受教育水平户主、大型规模家庭有更高的致贫风险,女性成员比例、抚养比等因素对农户贫困影响较小。激发农户内生动力、大力发展特色化和规模化农业、增加农户就业机会、加强针对农民工、女性务工人员和病残群体的社会保障等减贫政策制定实施是实现脱贫攻坚目标的重要途径。  相似文献   

景电灌区移民对祁连山植被恢复的相对生态价值          下载免费PDF全文

赵建林  康德奎  彭维恩  王建礼  史中兴  陈天顺  董志洋  汪杰  常兆丰 《干旱区地理》2020,43(1):182-189

近些年来，生态系统的服务价值研究已成为生态学以及生态经济学领域中的一个热点问题。祁连山被称为伸进西北干旱区的一座湿岛，在我国“一带一路”建设中占有重要地位。景电灌区兴建以来从祁连山移出了大量农牧民。那么，景电灌区移民对祁连山植被恢复的生态价值如何呢？以景电灌区移民涉及到的祁连山东端景泰、古浪、天祝3县山区为研究区，用价值工程方法对从祁连山区向景电灌区移民退耕退牧还林还草的生态价值做了分析，并与模型因子当量法的计算结果进行了比较。结果表明：祁连山向景电灌区移民退耕退牧还林还草总的生态价值为37.458 1×10⁸元。其中，退耕还林还草的生态价值为37.438 6×0⁸元，退牧后草场植被盖度增加的生态价值为194.79×104元。计算结果为用COSTANZA和谢高地模型因子当量法计算得的祁连山向景电灌区移民退耕退牧还林还草总的生态服务价值40.054 0×0⁸元的93.52%。两种方法计算结果祁连山向景电灌区移民退耕退牧还林还草总的生态价值为景电工程年总成本1.45×0⁸元的25.8~27.6倍。两种计算结果一致表明，景电灌区生态移民对祁连山植被恢复的生态价值十分突出。由此也可以看出，COSTANZA和谢高地模型因子当量法适用于祁连山的生态服务价值分析。  相似文献